These are shot with the Canon 85mm f1.2 lens, which is among the fastest lenses available. It is very costly, heavy and highly worshipped by many photographes for two reasons: it allows you to shoot in VERY low light; it produces a very intense look with very little depth of field.
Notice that there is some yellow cast on the left side of Nicole's face. There was a small tungsten focusing lamp which emitted enough light to affect the 1.2 exposure.